Preparation of a high-coordinated-silicon-centered spiro-cyclic compound-Reference-Cited by-同舟云学术

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Preparation of a high-coordinated-silicon-centered spiro-cyclic compound

Published:2024 Issue:27 Volume:53 Page:11410-11416
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kushvaha Saroj Kumar¹^ORCID,Gorantla Sai Manoj N. V. T.²^ORCID,Kallenbach Paula¹,Herbst-Irmer Regine¹^ORCID,Stalke Dietmar¹^ORCID,Roesky Herbert W.¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Georg-August Universität, Göttingen, Germany

2. Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, University of Tromsø – The Arctic University of Norway, N-9037 Tromsø, Norway

Abstract

Herein, we report preparation of a hyper-coordinated silicon-centered spirocyclic compound. This spirocyclic compound contains a silicon–silicon bond which has been rarely observed in silicon based spirocyclic compounds.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00627E

Reference44 articles.

1. High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

2. Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms

3. Reactions of Amidinate-Supported Silylene with Organoboron Dihalides

4. Synthesis and Structure of a Stable Silylene

5. An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

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