Control of the geometry and anisotropy driven by the combination of steric and anion coordination effects in CoII complexes with N6-tripodal ligands: the impact of the size of the ligand on the magnetization relaxation time

Author:

Landart Aritz1ORCID,Quesada-Moreno María Mar2ORCID,Palacios María A.1ORCID,Li Yanling3ORCID,Ozerov Mykhaylo4ORCID,Krzystek J.4,Colacio Enrique1ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain

2. Departamento de Química Física y Analítica, Facultad de Ciencias Experimentales, Universidad de Jaén, Campus Las Lagunillas, 23071 Jaén, Spain

3. Sorbonne Université Institut Parisien de Chimie Moléculaire, CNRS UMR 8232 4 place Jussieu 75252, Paris cedex 5, France

4. National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, USA

Abstract

Field-induced and hidden Co(ii) SIMs with N6-tripodal ligands exhibit size-dependent magnetic relaxation time.

Funder

Junta de Andalucía

Universidad de Granada

Agencia Estatal de Investigación

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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