Mechanistic insights into radical formation and functionalization in copper/<i>N</i>-fluorobenzenesulfonimide radical-relay reactions-Reference-Cited by-同舟云学术

Mechanistic insights into radical formation and functionalization in copper/N-fluorobenzenesulfonimide radical-relay reactions

Published:2024 Issue:4 Volume:15 Page:1364-1373
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mandal Mukunda¹²^ORCID,Buss Joshua A.³^ORCID,Chen Si-Jie³^ORCID,Cramer Christopher J.¹^ORCID,Stahl Shannon S.³^ORCID

Affiliation:

1. Department of Chemistry, Chemical Theory Center, and Supercomputing Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA

2. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

3. Department of Chemistry, University of Wisconsin–Madison, 1101 University Avenue, Madison, WI 53706, USA

Abstract

Copper-catalysed radical-relay reactions that employ N-fluorobenzenesulfonamide (NFSI) as the oxidant have emerged as highly effective methods for C(sp3)–H functionalization.

Funder

Alexander von Humboldt-Stiftung

National Institute of General Medical Sciences

University of Minnesota

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC03597B

Reference70 articles.

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5. Radical C(sp3)–H functionalization and cross-coupling reactions

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