Enantioselective hydrogenation of cyclic tetrasubstituted-olefinic dehydroamino acid derivatives-Reference-Cited by-同舟云学术

Enantioselective hydrogenation of cyclic tetrasubstituted-olefinic dehydroamino acid derivatives

Published:2021 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wan Feng¹²³⁴⁵,Wang Nan⁶⁷⁸⁹,Zhu Yuxin¹²³⁴⁵,Tang Chuyan¹²³⁴⁵,Claverie Jerome¹⁰¹¹¹²¹³¹⁴^ORCID,Tang Wenjun¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Bio-Organic and Natural Products Chemistry

2. Center for Excellence in Molecular Synthesis

3. Shanghai Institute of Organic Chemistry

4. Chinese Academy of Sciences

5. 345 Ling Ling Road

6. School of Physical Science and Technology

7. ShanghaiTech University

8. Shanghai 200031

9. China

10. Department of Chemistry

11. University of Sherbrooke

12. 2500 Blvd de l’Universit

13. Sherbrooke

14. Canada

Abstract

The Rh-ArcPhos catalyst has enabled the asymmetric hydrogenation of cyclic tetrasubstituted-olefinic dehydroamino acid derivatives, affording α-acylamino-β-alkyl tetrahydropyranones with two contiguous chiral centers in up to 96% ees and 1000 TONs.

Funder

Science and Technology Commission of Shanghai Municipality

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01277K

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2. B.Bosnich , Asymmetric Catalysis , Martinus Nijhoff , New York , 1986

3. I.Ojima , Catalytic Asymmetric Synthesis , VCH , New York , 1993

4. H.Brunner and W.Zettlmeier , Handbook of Enantioselective Catalysis , VCH , Weinheim , 1993

5. R.Noyori , Asymmetric Catalysis in Organic Synthesis , Wiley , New York , 1994

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