Semifluorinated, kinked polyarylenes via direct arylation polycondensation

Author:

Kempe Fabian123ORCID,Riehle Felix4563,Komber Hartmut783ORCID,Matsidik Rukiya123,Walter Michael95103ORCID,Sommer Michael123ORCID

Affiliation:

1. Chemnitz University of Technology

2. 09111 Chemnitz

3. Germany

4. Institute for Macromolecular Chemistry

5. University of Freiburg

6. 79104 Freiburg

7. Leibniz Institute of Polymer Research

8. 01069 Dresden

9. Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT)

10. 79110 Freiburg

Abstract

The Tg of semifluorinated polyarylenes made via DAP is varied between 35–195 °C depending on side chain, but solubilities are much less side chain dependent. This is explained by interactions between alkoxyphenyl and tetrafluorobenzene units.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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