Facile activation of alkynes with a boraguanidinato-stabilized germylene: a combined experimental and theoretical study-Reference-Cited by-同舟云学术

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Facile activation of alkynes with a boraguanidinato-stabilized germylene: a combined experimental and theoretical study

Published:2017 Issue:36 Volume:46 Page:12339-12353
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Böserle Jiří¹²³⁴⁵,Zhigulin Grigory⁶⁷⁸,Štěpnička Petr⁹¹⁰¹¹¹²⁵^ORCID,Horký Filip⁹¹⁰¹¹¹²⁵,Erben Milan¹²³⁴⁵,Jambor Roman¹²³⁴⁵,Růžička Aleš¹²³⁴⁵,Ketkov Sergey⁶⁷⁸,Dostál Libor¹²³⁴⁵^ORCID

Affiliation:

1. Department of General and Inorganic Chemistry

2. Faculty of Chemical Technology

3. University of Pardubice

4. CZ-532 10 Pardubice

5. Czech Republic

6. G. A. Razuvaev Institute of Organometallic Chemistry RAS

7. 603950 Nizhny Novgorod

8. Russian Federation

9. Department of Inorganic Chemistry

10. Faculty of Science

11. Charles University

12. CZ-12840 Prague

Abstract

A comprehensive study of the activation of various alkynes by boraguanidinato-stabilized germylene is presented.

Funder

Czech Science Foundation

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01950E

Reference115 articles.

1. Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured Sn II and Pb II alkyls, M[CH(SiMe3)2]2

2. Tris[bis(trimethylsilyl)methyl]tin(III), R3Sn·: an unusually stable stannyl radical, from photolysis of R2Sn

3. Monomeric, volatile bivalent amides of group IVBelements, M(NR12)2and M(NR1R2)2(MGe, Sn, or Pb; R1Me3Si, R2Me3C)

4. Subvalent Group 4B metal alkyls and amides. Part I. The synthesis and physical properties of kinetically stable bis[bis(trimethysilyl)methyl]-germanium(II), -tin(II), and -lead(II)

5. Di- and Trivalent Trimethylsilyl-Substituted Tin Amides and Related Compounds Such as Sn[N(SiMe3)2]2 or 3

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1. Recent advances in the chemistry of isolable carbene analogues with group 13–15 elements;Chemical Society Reviews;2024

2. Reversible hydrosilane addition to pyridines enabled by low-coordinate Ca(ii) and Yb(ii) hydrides;Inorganic Chemistry Frontiers;2024

3. REDUCTION PROPERTIES OF GERMANIUM DICHLORIDE WITH RESPECT TO THE REDOX-ACTIVE MONOIMINOACENAPHTENONE dpp-MIAN;Journal of Structural Chemistry;2023-02

4. N-heterocyclic germylenes and stannylenes: Synthesis, reactivity and catalytic application in a nutshell;Advances in Organometallic Chemistry;2020

5. Reactivity of boraguanidinato germylenes toward carbonyl compounds and isocyanides: C–O, C–F and C–N bond activation;Dalton Transactions;2020

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