Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

Author:

Xie Long-Yong1234,Peng Sha1234,Yang Li-Hua1234,Peng Cun1234,Lin Ying-Wu5674ORCID,Yu Xianyong5894,Cao Zhong101112134ORCID,Peng Yu-Yu101112134,He Wei-Min1234ORCID

Affiliation:

1. Department of Chemistry and Bioengineering

2. Hunan University of Science and Engineering

3. Yongzhou 425100

4. China

5. School of Chemistry and Chemical Engineering

6. University of South China

7. Hengyang 421001

8. Hunan University of Science and Technology

9. Xiangtan 411201

10. Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation

11. Changsha University of Science and Technology

12. Changsha

13. 410114

Abstract

Aryl radicals were generated for the first time from aryl acyl peroxides in ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer.

Funder

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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