Design of a fluorescent and clickable Ag38(SRN3)24 nanocluster platform: synthesis, modeling and self-assembling

Author:

Campi Gaetano123ORCID,Suber Lorenza423ORCID,Righi Giuliana5673ORCID,Primitivo Ludovica56738ORCID,De Angelis Martina56738,Caschera Daniela923ORCID,Pilloni Luciano101112133,Del Giudice Alessandra8673ORCID,Palma Amedeo423,Satta Mauro923ORCID,Fortunelli Alessandro14153ORCID,Sementa Luca16153ORCID

Affiliation:

1. CNR-Istituto di Cristallografia

2. Rome

3. Italy

4. CNR-Istituto di Struttura della Materia

5. CNR-IBPM-c/o Dip. Chimica

6. Sapienza Università di Roma

7. 00185 Rome

8. Dip. Chimica

9. CNR-Istituto per lo Studio dei Materiali Nanostrutturati

10. ENEA SSPT-PROMAS-MATPRO

11. Materials Technology Division

12. Casaccia Research Centre

13. 00123 Rome

14. CNR-Istituto di Chimica dei Composti Organometallici

15. 56127 Pisa

16. CNR-Istituto per i Processi Chimico Fisici

Abstract

Fluorescent Ag38(SRN3)24 nanoclusters with the novel presence of terminal azido groups for easily “click”-binding a wide set of molecular species and their self-assembling in lamellar and hexagonal superstructures permeated by nanoregion defects.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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