P(<scp>v</scp>) intermediate-mediated E1cB elimination for the synthesis of glycals-Reference-Cited by-同舟云学术

P(v) intermediate-mediated E1cB elimination for the synthesis of glycals

Published:2022 Issue:19 Volume:13 Page:5588-5596
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Fen¹,Huang Haiyang¹^ORCID,Sun Longgen¹,Yan Zeen¹,Tan Xiao¹,Li Jing¹,Luo Xinyue¹,Ding Haixin¹,Xiao Qiang¹^ORCID

Affiliation:

1. Key Laboratory of Organic Chemistry, Institute of Organic Chemistry, Jiangxi Science & Technology Normal University, Nanchang 330013, Jiangxi Province, China

Abstract

A novel glucosylphosphonium-hydrolysis induced E1cB-elimination provides a highly efficient, practical and scalable method for the synthesis of glycals with good compatibility and excellent yields.

Funder

National Natural Science Foundation of China

Jiangxi Provincial Department of Science and Technology

Jiangxi Science and Technology Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01423H

Reference75 articles.

1. CCCVII.—Influence of poles and polar linkings on the course pursued by elimination reactions. Part V. The mechanism of thermal decomposition of quaternary phosphonium hydroxides