Giant exchange coupling and field-induced slow relaxation of magnetization in Gd2@C79N with a single-electron Gd

Giant exchange coupling and field-induced slow relaxation of magnetization in Gd2@C79N with a single-electron Gd–Gd bond

Published:2018 Issue:23 Volume:54 Page:2902-2905
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Velkos G.¹²³^ORCID,Krylov D. S.¹²³,Kirkpatrick K.⁴⁵⁶⁷^ORCID,Liu X.⁴⁵⁶⁷^ORCID,Spree L.¹²³,Wolter A. U. B.¹²³,Büchner B.¹²³,Dorn H. C.⁴⁵⁶⁷⁸^ORCID,Popov A. A.¹²³^ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research

2. Dresden 01069

3. Germany

4. Department of Chemistry

5. Virginia Polytechnic Institute and State University

6. Blacksburg

7. USA

8. Virginia Tech Carilion Research Institute

Abstract

Single-electron Gd–Gd bond in Gd₂@C₇₉N results in giant ferromagnetic coupling between local 4f magnetic moments and unpaired electron spin.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC00112J

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