From cyclic (alkyl)(amino)carbene (CAAC) precursors to fluorinating reagents. Experimental and theoretical study-Reference-Cited by-同舟云学术

From cyclic (alkyl)(amino)carbene (CAAC) precursors to fluorinating reagents. Experimental and theoretical study

Published:2023 Issue:28 Volume:52 Page:9562-9572
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gruden Evelin¹^ORCID,Prinčič Griša Grigorij²,Hočevar Jan²,Iskra Jernej²^ORCID,Kvíčala Jaroslav³,Tavčar Gašper¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry and Technology, “Jožef Stefan” Institute, Jamova cesta 39, Ljubljana, Slovenia

2. Department of Chemistry and Biochemistry, University of Ljubljana, Faculty of Chemistry and Chemical Technology, Večna pot 113, 1000 Ljubljana, Slovenia

3. Department of Organic Chemistry, University of Chemistry and Technology, Technická 5, 166 28 Prague 6, Prague, Czech Republic

Abstract

A series of CAAC-based fluoride compounds has been prepared. Structural relationship between the compounds was investigated by DFT calculations, while their fluoride donating ability was tested on various organic substrates.

Funder

Grantová Agentura České Republiky

Javna Agencija za Raziskovalno Dejavnost RS

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01476B

Reference60 articles.

1. Monofluorination of Organic Compounds: 10 Years of Innovation

2. Transition metal catalysis and nucleophilic fluorination

3. The Fluorination of C−H Bonds: Developments and Perspectives

4. Where Does the Fluorine Come From? A Review on the Challenges Associated with the Synthesis of Organofluorine Compounds

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