Evidence for zero-field slow magnetic relaxation in a Co(<scp>ii</scp>) complex with a pseudo-tetrahedral N<sub>2</sub>I<sub>2</sub> environment-Reference-Cited by-同舟云学术

Evidence for zero-field slow magnetic relaxation in a Co(ii) complex with a pseudo-tetrahedral N₂I₂ environment

Published:2022 Issue:31 Volume:51 Page:11916-11921
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yureva E. A.¹^ORCID,Korchagin D. V.¹^ORCID,Anichkin A. A.¹²^ORCID,Shilov G. V.¹^ORCID,Babeshkin K. A.³^ORCID,Efimov N. N.³^ORCID,Palii A. V.¹^ORCID,Aldoshin S. M.¹^ORCID

Affiliation:

1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1, Acad. Semenov prosp., 142432 Chernogolovka, Moscow Region, Russia

2. Faculty of Fundamental Physical and Chemical Engineering, Moscow State University, 1-3, Leninskiye Gory, 119991 Moscow, Russia

3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31, Leninsky prosp., 119991 Moscow, Russia

Abstract

We report a unique pseudo-tetrahedral complex CoII(dmpz)2I2 with an N2I2 local coordination environment, exhibiting slow magnetic relaxation at zero dc field.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01336C

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