Sonocrystallization induced thermally activated delayed fluorescence via distortion of molecular geometry

Author:

Maggiore Antonio12ORCID,Qu Yangyang1,Pander Piotr34ORCID,Dias Fernando B.5ORCID,Clavier Gilles1ORCID,Guillot Regis6ORCID,Altamura Davide7,Giannini Cinzia7,Maiorano Vincenzo2,Audebert Pierre1ORCID,Miomandre Fabien1

Affiliation:

1. Université Paris-Saclay, ENS Paris-Saclay, CNRS, PPSM, Gif-sur-Yvette, 91190, France

2. CNR-NANOTEC – Institute of Nanotechnology, c/o Campus Ecoteckne, Via Monteroni, 73100 Lecce, Italy

3. Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland

4. Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22B, 44-100 Gliwice, Poland

5. Department of Physics, University of Durham, South Road, Durham, DH1 3LE, UK

6. CNRS, Institut de chimie moléculaire et des matériaux d'Orsay, Université Paris-Saclay, Orsay, 91405, France

7. Institute of Crystallography CNR-IC, Via Amendola 122/O, Bari 70126, Italy

Abstract

We present a donor–acceptor molecule Phx-BzN which displays virtually no photoluminescence in solution but shows strong thermally activated delayed fluorescence (TADF) in form of microcrystals obtained by sonicating water suspension of the compound.

Funder

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

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