An unprecedented pyridine-based dinuclear mixed-valent ReI/VII oxo-bridged complex: a solvatochromic and AIE-active probe for nanomolar detection of picric acid and trinitrotoluene-Reference-Cited by-同舟云学术

An unprecedented pyridine-based dinuclear mixed-valent ReI/VII oxo-bridged complex: a solvatochromic and AIE-active probe for nanomolar detection of picric acid and trinitrotoluene

Published:2021 Issue:26 Volume:50 Page:9144-9157
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mukherjee Atasi¹²³⁴,Bhattacharya Suman¹⁵⁶⁷^ORCID,Chakravarty Manab¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. BITS-Pilani Hyderabad Campus

3. Hyderabad-500078

4. India

5. University of Malta

6. Msida

7. Malta

Abstract

Oxo-bridged mixed-valent binuclear Re^I/VI complex is synthesized using a twisted bulky pyridyl ligand. The complex shows solvatofluorochromic/AIE-feature and is utilized to detect picric acid/TNT in nanomolar range. The sensing is also explored in paper strip/soil.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01002F

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