Disorder and polymorphism in Cu(ii)-polyoxometalate complexes: [Cu1.5(H2O)7.5PW12O40]·4.75H2O, cis- & trans-[Cu2(H2O)10SiW12O40]·6H2O-Reference-Cited by-同舟云学术

Disorder and polymorphism in Cu(ii)-polyoxometalate complexes: [Cu1.5(H2O)7.5PW12O40]·4.75H2O, cis- & trans-[Cu2(H2O)10SiW12O40]·6H2O

Published:2016 Issue:28 Volume:18 Page:5327-5332
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Bajpe Sneha R.¹²³,Henke Sebastian⁴⁵⁶,Lee Jung-Hoon¹²³,Bristowe Paul D.¹²³,Cheetham Anthony K.¹²³

Affiliation:

1. Department of Materials Science and Metallurgy

2. University of Cambridge

3. Cambridge CB3 0FS, UK

4. Lehrstuhl für Anorganische Chemie II

5. Ruhr-Universität Bochum

6. 44780 Bochum, Germany

Abstract

Three highly crystalline Cu(ii)-polyoxometalate (POM) complexes, [Cu_1.5(H₂O)_7.5PW₁₂O₄₀]·4.75H₂O and cis- and trans-[Cu₂(H₂O)₁₀SiW₁₂O₄₀]·6H₂O, were successfully synthesized and characterized by single crystal and powder X-ray diffraction as well as thermogravimetric analysis.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CE/C5CE02088C

Reference54 articles.

1. M. T. Pope , Polyoxometalate Molecular Science , 2003 , pp. 3–31

2. Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions

3. Organic/Inorganic Supramolecular Assemblies and Synergy between Physical Properties

4. Recent progress in catalytic technology in japan

5. Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Polyoxometalate-based Cu(II) complexes as the photocatalyst for oxidation of toluene and photodegradation of metronidazole;Polyoxometalates;2024-12

2. Covalent conductive polymer chain and organic ligand ethylenediamine modified MXene-like-{AlW12O40} compounds for fully symmetric supercapacitors, electrochemical sensors and photocatalysis mechanisms;Journal of Materials Chemistry A;2020

3. A High‐Symmetrical 3D Pure Inorganic Photocatalyst Based on the Highest Connectivity of {AsW 12 O 40 } Heteropoly Blue and Potassium Ions;European Journal of Inorganic Chemistry;2018-08-29

4. Synthesis and Characterization of 0D–3D Copper-Containing Tungstobismuthates Obtained from the Lacunary Precursor Na9[B-α-BiW9O33];Inorganic Chemistry;2016-12-21