Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment

Author:

Fieser Megan E.1234ORCID,Palumbo Chad T.1234ORCID,La Pierre Henry S.56789ORCID,Halter Dominik P.56789ORCID,Voora Vamsee K.1234ORCID,Ziller Joseph W.1234ORCID,Furche Filipp1234ORCID,Meyer Karsten56789ORCID,Evans William J.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. Irvine

4. USA

5. Department of Chemistry and Pharmacy

6. Inorganic Chemistry

7. Friedrich-Alexander-University Erlangen-Nürnberg (FAU)

8. D-91058 Erlangen

9. Germany

Abstract

Nd, like U, prefers a f4 configuration with the tris(aryloxide)arene ligand rather than the 4f35d1 configuration found in tris(cyclopentadienyl) complexes.

Funder

Bundesministerium für Bildung und Forschung

Division of Chemistry

Division of Graduate Education

Friedrich-Alexander-Universität Erlangen-Nürnberg

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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