Structural dynamics in Ni–Fe catalysts during CO2 methanation – role of iron oxide clusters

Author:

Serrer Marc-André12345,Gaur Abhijeet12345ORCID,Jelic Jelena5264ORCID,Weber Sebastian12345ORCID,Fritsch Charlotte12345ORCID,Clark Adam H.78910ORCID,Saraçi Erisa12345,Studt Felix12345ORCID,Grunwaldt Jan-Dierk12345ORCID

Affiliation:

1. Institute for Chemical Technology and Polymer Chemistry

2. Karlsruhe Institute of Technology (KIT)

3. 76131 Karlsruhe

4. Germany

5. Institute of Catalysis Research and Technology

6. 76344 Eggenstein-Leopoldshafen

7. SuperXAS beamline

8. Paul Scherrer Institut (PSI)

9. 5232 Villigen

10. Switzerland

Abstract

Operando XAS coupled with MES supported by DFT unravel the highly dynamic nature of Ni–Fe catalysts during CO2 methanation and beneficial formation of iron oxide clusters.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

European Synchrotron Radiation Facility

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference79 articles.

1. Put the Sun in the Tank: Future Developments in Sustainable Energy Systems

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3. M. Sterner , Erneuerbare Energien und Energieeffizienz - Renewable Energies and Energy Efficiency , Kassel University Press GmbH , Kassel , 2009

4. Linking the Power and Transport Sectors—Part 1: The Principle of Sector Coupling

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