Visible-light-enabled stereoselective synthesis of functionalized cyclohexylamine derivatives <i>via</i> [4 + 2] cycloadditions-Reference-Cited by-同舟云学术

Visible-light-enabled stereoselective synthesis of functionalized cyclohexylamine derivatives via [4 + 2] cycloadditions

Published:2024 Issue:17 Volume:15 Page:6507-6514
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lu Yi-Nan¹,Che Chao¹^ORCID,Zhen Guangjin¹,Chang Xin¹,Dong Xiu-Qin¹^ORCID,Wang Chun-Jiang¹²^ORCID

Affiliation:

1. College of Chemistry and Molecular Sciences, Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, Wuhan University, Wuhan, Hubei, 430072, China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 230021, China

Abstract

Photocatalyzed [4 + 2] cycloaddition of benzocyclobutylamines with α-substituted vinylketones afforded benzocyclohexylamines in moderate to good yields with excellent diastereoselectivities. An asymmetric version of this was preliminarily investigated.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Natural Science Foundation of Hubei Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00667D

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1. New Methods of Resolution and Purification of Racemic and Diastereomeric Amino Alcohol Derivatives Using Boric Acid and Chiral 1,1‘-Bi-2-naphthol

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3. Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

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