Cooperative intermolecular S–Cl⋯O and F⋯F associations in the crystal packing of α,ω-di(sulfonyl chloride) perfluoroalkanes, ClSO2(CF2)nSO2Cl, where n = 4, 6
Author:
Affiliation:
1. Department of Materials Science and Engineering
2. Clemson University
3. Advanced Materials Research Laboratory
4. Anderson
5. USA
6. Department of Chemistry
7. Hunter Laboratories
8. Clemson
Abstract
Halogen bonding between neighboring sulfonyl chloride groups and short fluorine–fluorine contacts supports crystal formation in the title compounds.
Funder
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ00536B
Reference49 articles.
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2. A useful synthesis of ω-iodoperfluoroalkanesulfonyl fluorides and perfluoroalkane-α,ω-bis-sulfonyl fluorides
3. Synthesis and characterization of 1,2-bis (chlorosulfonyl) tetrafluoroethane and 1,2-bis (fluorosulfonyl) tetrafluoroethane
4. I. Sharif , S.Creager and D.DesMarteau , in Handbook of Fluoropolymer Science and Technology , ed. D. W. Smith, Jr. , S. T. Iacono and S. S. Iyer , John Wiley & Sons, Inc ., Hoboken, NJ , 2014 , Ch. 22, and references therein
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