Cooperative intermolecular S–Cl⋯O and F⋯F associations in the crystal packing of α,ω-di(sulfonyl chloride) perfluoroalkanes, ClSO2(CF2)nSO2Cl, where n = 4, 6

Author:

Liu Xiaolin12345,McMillen Colin D.62785,Thrasher Joseph S.62345ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. Clemson University

3. Advanced Materials Research Laboratory

4. Anderson

5. USA

6. Department of Chemistry

7. Hunter Laboratories

8. Clemson

Abstract

Halogen bonding between neighboring sulfonyl chloride groups and short fluorine–fluorine contacts supports crystal formation in the title compounds.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference49 articles.

1. Studies on deiodo-sulfination. Part I. Studies on the deiodo-sulfination of perfluoroalkyl iodides

2. A useful synthesis of ω-iodoperfluoroalkanesulfonyl fluorides and perfluoroalkane-α,ω-bis-sulfonyl fluorides

3. Synthesis and characterization of 1,2-bis (chlorosulfonyl) tetrafluoroethane and 1,2-bis (fluorosulfonyl) tetrafluoroethane

4. I. Sharif , S.Creager and D.DesMarteau , in Handbook of Fluoropolymer Science and Technology , ed. D. W. Smith, Jr. , S. T. Iacono and S. S. Iyer , John Wiley & Sons, Inc ., Hoboken, NJ , 2014 , Ch. 22, and references therein

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