Synthesis of six-coordinate mono-, bis-, and tris(tetrazolato) complexes via [3 + 2] cycloadditions of nitriles to silicon-bound azido ligands-Reference-Cited by-同舟云学术

Synthesis of six-coordinate mono-, bis-, and tris(tetrazolato) complexes via [3 + 2] cycloadditions of nitriles to silicon-bound azido ligands

Published:2016 Issue:43 Volume:45 Page:17141-17152
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Portius Peter¹²³⁴,Davis Martin¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Sheffield

3. Sheffield S3 7HF

4. United Kingdom

Abstract

The unusual situation presented by a silicon centre coordinating four 1,3-dipolar ligands is exploited in thermally activated cycloaddition reactions with nitriles that lead to six-coordinate poly(tetrazolato) complexes of silicon.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02867E

Reference69 articles.

1. Experimental and Theoretical Study of the Coordination of 1,2,4-Triazolato, Tetrazolato, and Pentazolato Ligands to the [K(18-crown-6)]+ Fragment

2. Remarkable Tuning of the Coordination and Photophysical Properties of Lanthanide Ions in a Series of Tetrazole-Based Complexes

3. Homoleptic Iron(II) Complexes with the Ionogenic Ligand 6,6′-Bis(1H-tetrazol-5-yl)-2,2′-bipyridine: Spin Crossover Behavior in a Singular 2D Spin Crossover Coordination Polymer

4. Synthesis, characterization, and biological evaluation of new tetrazole-based platinum(II) and palladium(II) chlorido complexes — Potent cisplatin analogues and their trans isomers

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