A kinetic study of the CH2OO Criegee intermediate self-reaction, reaction with SO2 and unimolecular reaction using cavity ring-down spectroscopy
Author:
Affiliation:
1. School of Chemistry
2. University of Bristol
3. Bristol
4. UK
5. Centre for Atmospheric Science
6. School of Earth
7. Atmospheric and Environmental Sciences
8. University of Manchester
9. Manchester
Abstract
A rate coefficient is reported for the CH2OO self-reaction and evidence presented for SO2-catalysed CH2OO isomerization or intersystem crossing.
Funder
Natural Environment Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04198D
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4. J. G. Calvert , R.Atkinson, J. A.Kerr, S.Madronich, G. K.Moortgat, T. J.Wallington and G.Yarwood, The mechanims of atmospheric oxidation of the alkenes, Oxford University Press, 2000
5. Mechanism of HOx Formation in the Gas-Phase Ozone−Alkene Reaction. 1. Direct, Pressure-Dependent Measurements of Prompt OH Yields
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