Unexpected reversal of reactivity in organic functionalities when immobilized together in a metal–organic framework (MOF)-Reference-Cited by-同舟云学术

Unexpected reversal of reactivity in organic functionalities when immobilized together in a metal–organic framework (MOF)

Published:2024 Issue:5 Volume:9 Page:445-448
ISSN:2058-9689
Container-title:Molecular Systems Design & Engineering
language:en
Short-container-title:Mol. Syst. Des. Eng.

Author:

Matseketsa Pricilla¹^ORCID,Mafukidze Donovan¹^ORCID,Pothupitiya Lahiru¹^ORCID,Otuonye Udo P.¹,Mutlu Yasemin Çimen²³,Averkiev Boris B.¹,Gadzikwa Tendai¹^ORCID

Affiliation:

1. Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, USA

2. Department of Chemistry, Faculty of Science, Eskisehir Technical University, 26470 Eskişehir, Turkey

3. Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA

Abstract

The reactivity of hydroxyl-bearing MOF linkers with isocyanates is influenced by their mutual confinement with amine-bearing linkers within the pores of the framework.

Funder

Army Research Office

National Institute of General Medical Sciences

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/ME/D3ME00185G

Reference29 articles.

1. Metal-organic frameworks: structure, properties, methods of synthesis and characterization

2. Visualization and Quantification of Geometric Diversity in Metal–Organic Frameworks

3. Applications of reticular diversity in metal–organic frameworks: An ever-evolving state of the art

4. Exploitation of Intrinsic Confinement Effects of MOFs in Catalysis

5. Nanochannel-Promoted Polymerization of Substituted Acetylenes in Porous Coordination Polymers

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