Spatial dynamics of lithiation and lithium plating during high-rate operation of graphite electrodes

Author:

Finegan Donal P.123ORCID,Quinn Alexander123ORCID,Wragg David S.456ORCID,Colclasure Andrew M.123ORCID,Lu Xuekun7891011,Tan Chun7891011ORCID,Heenan Thomas M. M.7891011ORCID,Jervis Rhodri7891011ORCID,Brett Dan J. L.7891011ORCID,Das Supratim1213143ORCID,Gao Tao1213143,Cogswell Daniel A.1213143ORCID,Bazant Martin Z.1213143ORCID,Di Michiel Marco151617ORCID,Checchia Stefano18192021,Shearing Paul R.7891011ORCID,Smith Kandler123ORCID

Affiliation:

1. National Renewable Energy Laboratory

2. Golden

3. USA

4. Centre for Materials and Nanotechnology, University of Oslo

5. 0315 Oslo

6. Norway

7. Electrochemical Innovation Laboratory, Department of Chemical Engineering

8. University College London

9. London

10. UK

11. The Faraday Institution

12. Department of Chemical Engineering

13. Massachusetts Institute of Technology

14. Cambridge

15. ESRF-The European Synchrotron

16. 38000 Grenoble

17. France

18. MAX IV Laboratory

19. University of Lund

20. Lund

21. Sweden

Abstract

Favorable conditions for lithium plating on graphite electrodes occur at high charge rates, causing accelerated degradation and safety concerns. A detailed map of lithiation and lithium plating dyamics is presented.

Funder

U.S. Department of Energy

Royal Academy of Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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