Coordination-driven assembly of actinide-organic polyrotaxanes involving crown ether macrocycles

Author:

Wang Jing-yang12345,Wu Qun-yan67385ORCID,Wang Shuai67385,Huang Zhi-wei12345,Hu Kong-qiu67385,Yu Ji-pan67385,Mei Lei67385ORCID,Zhang Meng91011125ORCID,Chai Zhi-fang12345,Shi Wei-qun12345ORCID

Affiliation:

1. Engineering Laboratory of Advanced Energy Materials

2. Ningbo Institute of Industrial Technology

3. Chinese Academy of Sciences

4. Ningbo 315201

5. China

6. Laboratory of Nuclear Energy Chemistry

7. Institute of High Energy Physics

8. Beijing 100049

9. Fundamental Science on Nuclear Safety and Simulation Technology Laboratory

10. College of Nuclear Science and Technology

11. Harbin Engineering University

12. Harbin 150001

Abstract

Using macrocyclic DB24C8 as a new kind of host molecule for a pseudorotaxane ligand, actinide-linked crown ether-based coordination polyrotaxanes, UCER-1 and UCER-2, that are linked by two different uranyl nodes, have been synthesised for the first time.

Funder

National Natural Science Foundation of China

National Science Fund for Distinguished Young Scholars

Youth Innovation Promotion Association

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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