Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF-Reference-Cited by-同舟云学术

Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF

Published:2024 Issue:6 Volume:14 Page:4244-4251
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Thangavel Kavipriya¹²³^ORCID,Folli Andrea⁴^ORCID,Fischer Marcus⁵^ORCID,Hartmann Martin⁵^ORCID,Murphy Damien M.²^ORCID,Pöppl Andreas¹^ORCID

Affiliation:

1. Felix Bloch Institute for Solid State Physics, Leipzig University, Linnestraße 5, 04103 Leipzig, Germany

2. School of Chemistry, Cardiff University, Main Building, Cardiff CF10 3AT, UK

3. National High Magnetic Field Laboratory, Tallahassee, Florida 32310, USA

4. Net Zero Innovation Institute, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Translational Research Hub, Maindy Road, CF24 4HF, Cardiff, UK

5. Erlangen Center for Interface Research and Catalysis (ECRC), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058, Erlangen, Germany

Abstract

The flexibility of the MIL-53(M) metal–organic framework (MOF) has been elucidated through EPR spectroscopy, in liquid adsorption processes.

Funder

HORIZON EUROPE Marie Sklodowska-Curie Actions

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D3RA07952J

Reference27 articles.

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3. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy

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5. New insights into solvent-induced structural changes of 13C labelled metal–organic frameworks by solid state NMR