Selective recognition and reversible encapsulation of tetrameric alcohol clusters <i>via</i> hydrogen bonds using a perfluorinated dinuclear nickel(<scp>ii</scp>) complex-Reference-Cited by-同舟云学术

Selective recognition and reversible encapsulation of tetrameric alcohol clusters via hydrogen bonds using a perfluorinated dinuclear nickel(ii) complex

Published:2024 Issue:23 Volume:26 Page:3014-3020
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Habuka Yusuke¹,Usui Hirotomo¹,Okawa Mizuki¹,Shinohara Takanori²,Yuge Hidetaka²,Mao Yuchen³,Gong Jin³^ORCID,Richards Gary J.¹^ORCID,Hori Akiko¹^ORCID

Affiliation:

1. Graduate School of Engineering and Science, Shibaura Institute of Technology, Fukasaku 307, Minuma-ku, Saitama 337-8570, Japan

2. Department of Chemistry, School of Science, Kitasato University, Kitasato 1-15-1, Minami-ku, Sagamihara 252-0373, Japan

3. Graduate School of Organic Materials Science, Yamagata University, Jonan 4-3-16, Yonezawa, Yamagata 992-8510, Japan

Abstract

A perfluorinated Ni(ii) complex encapsulates MeOH, forming unique tetrameric clusters stabilized by hydrogen bonding in the crystal to achieve remarkable uptake of MeOH over EtOH and water, demonstrating potential for separation and sensing.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00166D

Reference49 articles.

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