Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds-Reference-Cited by-同舟云学术

Light- or oxidation-triggered CO release from [MnI(CO)3(κ3-L)] complexes: reaction intermediates and a new synthetic route to [MnIII/IV2(μ-O)2(L)2] compounds

Published:2016 Issue:43 Volume:45 Page:17464-17473
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sachs Ulf¹²³⁴,Schaper Gerrit¹²³⁴,Winkler Daniela¹²³⁴,Kratzert Daniel¹²³⁴,Kurz Philipp¹²³⁴

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Albert-Ludwigs-Universität Freiburg

3. 79104 Freiburg

4. Germany

Abstract

The substitution of the carbonyl ligands of [Mn^I(CO)₃(κ³-L)] complexes can be triggered in two different ways: by near-UV irradiation or by electrochemical oxidation of Mn^I to Mn^II.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02020H

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