Selective carbene transfer to amines and olefins catalyzed by ruthenium phthalocyanine complexes with donor substituents-Reference-Cited by-同舟云学术

Selective carbene transfer to amines and olefins catalyzed by ruthenium phthalocyanine complexes with donor substituents

Published:2021 Issue:6 Volume:50 Page:2023-2031
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cailler Lucie P.¹²³⁴⁵,Kroitor Andrey P.⁶⁷⁸⁹,Martynov Alexander G.⁶⁷⁸⁹^ORCID,Gorbunova Yulia G.⁶⁷⁸⁹¹⁰^ORCID,Sorokin Alexander B.¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Lyon

2. Université Claude Bernard Lyon 1

3. CNRS

4. IRCELYON

5. 69626 Villeurbanne

6. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

7. Russian Academy of Sciences

8. 119071 Moscow

9. Russia

10. N. S. Kurnakov Institute of General and Inorganic Chemistry

Abstract

A ruthenium phthalocyanine catalyzes the cyclopropanation of olefins (15 substr.) and single carbene insertion into N–H bonds of aromatic, heteroaromatic and aliphatic amines (20 substr.) with high selectivity and under practical reaction conditions.

Funder

Agence Nationale de la Recherche

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04090H

Reference98 articles.

1. Modern Organic Synthesis with α-Diazocarbonyl Compounds

2. Iron catalysts with N-ligands for carbene transfer of diazo reagents