Chlorine-mediated electrodeposition of hierarchical and hydrophobic copper electrocatalysts for efficient CO2 electroreduction to ethylene

Author:

Wu Yinqiong12,Feng Jiye1,Shi Danni1,Zhang Wenbiao13,Tang Yi3ORCID,Gao Qingsheng1ORCID

Affiliation:

1. College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, P. R. China

2. Shantou Power Supply Bureau of Guangdong Power Grid Co. Ltd, Shantou 515000, P. R. China

3. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials and Collaborative Innovation Centre of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China

Abstract

Hierarchical Cu dendrites fabricated via Cl-mediated electrodeposition afford high C2H4 efficiency in CO2 electroreduction thanks to not only the optimal hydrophobicity/aerophilicity, but also the mainly-exposed (100) and (110) facets.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Guangzhou Science and Technology Program key projects

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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