Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems-Reference-Cited by-同舟云学术

Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems

Published:2020 Issue:25 Volume:49 Page:8701-8709
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Do Dinh Cao Huan¹²³⁴⁵^ORCID,Vasko Petra¹²³⁴⁵^ORCID,Fuentes M. Ángeles¹²³⁴⁵^ORCID,Hicks Jamie¹²³⁴⁵^ORCID,Aldridge Simon¹²³⁴⁵^ORCID

Affiliation:

1. Inorganic Chemistry Laboratory

2. Department of Chemistry

3. University of Oxford

4. Oxford

5. UK

Abstract

Ring contraction reactions in electron-rich amino-Nacnac silylene complexes are driven by electron releasing and sterically unencumbered silicon-bound substituents.

Funder

Academy of Finland

Leverhulme Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01447H

Reference64 articles.

1. 129. Metal derivatives of NN′-diarylamidines

2. Synthesis, solution stereochemistry, and electron delocalization properties of bis(.beta.-iminoamino)nickel(II) complexes

3. Synthesis and properties of some β-diketimines derived from acetylacetone, and their metal complexes

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