Quantification of the hydride donor abilities of NADH, NADPH, and BH<sub>3</sub>CN<sup>−</sup> in water-Reference-Cited by-同舟云学术

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Quantification of the hydride donor abilities of NADH, NADPH, and BH₃CN⁻ in water

Published:2023 Issue:1 Volume:21 Page:85-88
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Mayer Robert J.¹^ORCID,Moran Joseph¹²^ORCID

Affiliation:

1. Institut de Science et d'Ingénierie Supramoléculaires (ISIS), CNRS UMR 7006, Université de Strasbourg, 8 Allée Gaspard Monge, 67000 Strasbourg, France

2. Institut Universitaire de France (IUF), 75005 Paris, France

Abstract

Despite their structural differences, the hydride donors BH3CN−, NADH, and NADPH were found to feature very similar kinetic hydride donor abilities in aqueous solution.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB02041F

Reference20 articles.

1. J. E.McMurry and T. P.Begley , The Organic Chemistry of Biological Pathways , Roberts and Company , Greenwood Village, CO , ed. 2nd, 2016

2. Cyanohydridoborate anion as a selective reducing agent

3. Thermodynamic and kinetic hydricities of metal-free hydrides

4. Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions

5. Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles,

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