Geometric, electronic and magnetic structures of S = 19/2 and S = 20/2 thiophene-2-carboxylate functionalized Mn12 single molecule magnets-Reference-Cited by-同舟云学术

Geometric, electronic and magnetic structures of S = 19/2 and S = 20/2 thiophene-2-carboxylate functionalized Mn12 single molecule magnets

Published:2015 Issue:1 Volume:44 Page:167-175
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rodriguez Jorge H.¹²³⁴,Ziegler Christopher J.⁵⁶⁷⁴

Affiliation:

1. Department of Physics and Astronomy

2. Purdue University

3. W. Lafayette

4. USA

5. Department of Chemistry

6. University of Akron

7. Akron

Abstract

Hydrogen bonding of water molecules to Mn₄O₄ inner cubane of S = 19/2 Mn₁₂ SMM gives rise to geometric and magnetic asymmetries. Two Mn ions hydrogen bonded to water molecules depart from their Mn⁴⁺(S = 3/2) states and acquire an incipient Mn³⁺(S = 4/2) character. The magnetic moment vectors of the cubane Mn ions are inequivalent.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02703E

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