The impact of boron atoms on clathrate-I silicides: composition range of the borosilicide K8−xBySi46−y-Reference-Cited by-同舟云学术

The impact of boron atoms on clathrate-I silicides: composition range of the borosilicide K8−xBySi46−y

Published:2021 Issue:4 Volume:50 Page:1274-1282
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jung Walter¹²³⁴⁵,Böhme Bodo¹²³,Hübner Julia M.¹²³,Burkhardt Ulrich¹²³,Borrmann Horst¹²³,Bobnar Matej¹²³,Nguyen Hong Duong¹²³⁶⁷,Pantenburg Ingo⁴⁵⁸⁹³,Etter Martin¹⁰¹¹³,Schwarz Ulrich¹²³^ORCID,Grin Yuri¹²³,Baitinger Michael¹²³^ORCID

Affiliation:

1. Max-Planck-Institut für Chemische Physik fester Stoffe

2. 01187 Dresden

3. Germany

4. Department für Chemie

5. Institut für Anorganische Chemie

6. Enviromental and Ressources Management Department

7. Quang Ninh Economic Zone Authority

8. Universität zu Köln

9. 50939 Köln

10. Deutsches Elektronen-Synchrotron (DESY)

11. 22607 Hamburg

Abstract

The clathrate-I borosilicide K_8−xB_ySi_46−y (0.8 ≤ x ≤ 1.2 and 6.4 ≤ y ≤ 7.2; space group Pm3̄n) was prepared in sealed tantalum ampoules between 900 °C and 1000 °C.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03339A

Reference38 articles.

1. The Physics and Chemistry of Inorganic Clathrates , ed. G. S. Nolas , Springer Series in Materials Science , 2014

2. Clathrate thermoelectrics

3. Sur les phases de type clathrate du silicium et des éléments apparentés (C, Ge, Sn) : Une approche historique

4. Thermoelectric clathrates of type I

5. Die verbindungen AII8BIII16BIV30 (AII ≡ Sr, Ba; BIII≡ Al, Ga; BIV ≡ Si, Ge, Sn) und ihre käfigstrukturen

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