Medium-sized rings: conformational preferences in cyclooctanone driven by transannular repulsive interactions-Reference-Cited by-同舟云学术

Medium-sized rings: conformational preferences in cyclooctanone driven by transannular repulsive interactions

Published:2019 Issue:8 Volume:21 Page:4331-4338
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Burevschi Ecaterina¹²³⁴^ORCID,Peña Isabel¹²³⁴^ORCID,Sanz M. Eugenia¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. King's College London

3. SE1 1DB London

4. UK

Abstract

Three conformers of cyclooctanone have been identified by broadband rotational spectroscopy. Cyclooctanone shows a strong preference to adopt a boat-chair conformation, driven by minimisation of repulsive non-bonded transannular interactions.

Funder

Engineering and Physical Sciences Research Council

FP7 People: Marie-Curie Actions

King's College London

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP07322H

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