Comparative study of CO<sub>2</sub>insertion into pincer supported palladium alkyl and aryl complexes-Reference-Cited by-同舟云学术

Comparative study of CO₂insertion into pincer supported palladium alkyl and aryl complexes

Published:2023 Issue:30 Volume:14 Page:8164-8179
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Deziel Anthony P.¹,Gahlawat Sahil²³^ORCID,Hazari Nilay¹^ORCID,Hopmann Kathrin H.²^ORCID,Mercado Brandon Q.¹

Affiliation:

1. Department of Chemistry, Yale University, P. O. Box 208107, New Haven, Connecticut, 06520, USA

2. Department of Chemistry, UiT The Arctic University of Norway, N-9307 Tromsø, Norway

3. Hylleraas Center for Quantum Molecular Sciences, UiT The Arctic University of Norway, 9037 Tromsø, Norway

Abstract

The synthesis of a range of PBP supported palladium pincer complexes with different alkyl ligands is described. The rates of CO2insertion into the alkyl group are quantified and rationalized based on the identity of the alkyl ligand.

Funder

National Science Foundation

Nevada Humanities

Norges Forskningsråd

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01459B

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