Is a strong axial crystal-field the only essential condition for a large magnetic anisotropy barrier? The case of non-Kramers Ho(iii) versus Tb(iii )-Reference-Cited by-同舟云学术

Is a strong axial crystal-field the only essential condition for a large magnetic anisotropy barrier? The case of non-Kramers Ho(iii) versus Tb(iii )

Published:2018 Issue:2 Volume:47 Page:357-366
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gupta Sandeep K.¹²³⁴^ORCID,Rajeshkumar Thayalan¹²³⁴,Rajaraman Gopalan¹²³⁴^ORCID,Murugavel Ramaswamy¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai-400076

4. India

Abstract

This study highlights that although strong axiality holds the key for designing high temperature SMMs based on non-Kramers ions, the strength of the equatorial ligand field, although small, cannot be ignored.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04020B

Reference60 articles.

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4. Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes

5. Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets via bridging ligand modification

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