Macrocycle polymeric networks based on a chair-like calix[4]pyrrole for the rapid and efficient adsorption of iodine from water

Author:

Zheng Zhiye1,Lin Qiuyuan1,Xie Linhuang1,Chen Xiaolong1,Zhou Huan1,Lin Kunhua1,Zhang Dengsong2ORCID,Chi Xiaodong3,Sessler Jonathan L.4ORCID,Wang Hongyu1ORCID

Affiliation:

1. Department of Chemistry, College of Science, Center for Supramolecular Chemistry & Catalysis, Shanghai University, 99 Shangda Road, Shanghai, 200444, P. R. China

2. International Joint Laboratory of Catalytic Chemistry, Department of Chemistry, Research Center of Nanoscience and Technology, College of Sciences, Shanghai University, Shanghai 200444, P. R. China

3. State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China

4. Department of Chemistry, The University of Texas at Austin, 105 E. 24th Street A5300, Austin, Texas, 78712, USA

Abstract

Two macrocycle polymeric networks (MPNs), C[4]P-TEPM and C[4]P-HEPM, were synthesized and found to exhibit iodine uptake capacities of 4.02 and 4.45 g g−1from a KI/I2solution, respectively. These values are among the highest reported for iodine adsorbent materials.

Funder

National Natural Science Foundation of China

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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