Sharing the salt bowl: counterion identity drives N-alkyl resorcinarene affinity for pyrophosphate in water

Author:

Twum Kwaku1ORCID,Iraj Sadraei Seyed2,Feder Jordan1,Taimoory S. Maryamdokht23ORCID,Rissanen Kari4ORCID,Trant John F.2ORCID,Beyeh Ngong Kodiah1ORCID

Affiliation:

1. Department of Chemistry, Oakland University, 146 Library Drive, Rochester, MI 48309-4479, USA

2. Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, Windsor, ON, N9B 3P4, Canada

3. University of Michigan, Department of Chemistry, Ann Arbor, MI, USA

4. University of Jyvaskyla, Department of Chemistry, P. O. Box 35, 40014 Jyvaskyla, Finland

Abstract

The binding affinity for pyrophosphate (PPi) in aqueous media by N-alkyl ammonium resorcinarene salts can be enhanced via using weakly coordinating counter anions and modifying the upper rims of the receptors and the lower rim hydroxyl groups.

Funder

Windsor Cancer Centre Foundation

Oakland University

University of Windsor

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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