Chiral <i>N</i>-triflylphosphoramide-catalyzed asymmetric hydroamination of unactivated alkenes: a hetero-ene reaction mechanism-Reference-Cited by-全球学者库

Chiral N-triflylphosphoramide-catalyzed asymmetric hydroamination of unactivated alkenes: a hetero-ene reaction mechanism

Published:2022 Issue:6 Volume:9 Page:1649-1661
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Na¹²³,Fan Li-Wen³,Zhang Jin³,Gu Qiang-Shuai⁴^ORCID,Lin Jin-Shun³,Chen Guo-Qiang¹,Liu Xin-Yuan³^ORCID,Yu Peiyuan³^ORCID

Affiliation:

1. College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518071, China

2. College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China

3. Department of Chemistry and Shenzhen Grubbs Institute, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen 518055, China

4. Academy for Advanced Interdisciplinary Studies and Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Abstract

A rare hetero-ene mechanism has been computationally elucidated to enable the activation of unactivated alkenes by moderately strong chiral N-triflylphosphoramide Brønsted acid catalysts.

Funder

National Natural Science Foundation of China

Shenzhen University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01874D

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