Research on the quantum confinement effect and enhanced luminescence of red-emitting P5+-doped CaAl12O19:Mn4+,Mg2+ phosphors

Author:

Fan Guodong12ORCID,Zhang Han12,Fan Di34,Jiang Rui5,Ruan Fangyi12,Li Nan12,Su Xiaoyan12

Affiliation:

1. College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, P. R. China

2. Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi'an 710021, P. R. China

3. Department of Information Engineering, Shaanxi Polytechnic Institute, Xianyang 712000, P. R. China

4. Department of Electronic and Electrical Engineering, University of Sheffield, Sheffield S10 2TN, UK

5. College of Geosciences, China University of Petroleum, Beijing, Changping 102249, P. R. China

Abstract

Substituting P5+ for Al3+ leads to charge imbalance, which will induce the formation of an electron trap and oxygen vacancy and further generate a quantum-confined electron trap, thereby improving the luminescence intensity and PLQY of phosphors.

Funder

National Natural Science Foundation of China

Key Science and Technology Program of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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