Solvent-induced structural diversity in tetranuclear Ni(ii) Schiff-base complexes: the first Ni4single-molecule magnet with a defective dicubane-like topology

Author:

Herchel Radovan12345ORCID,Nemec Ivan12345ORCID,Machata Marek12345,Trávníček Zdeněk12345

Affiliation:

1. Department of Inorganic Chemistry

2. Regional Centre of Advanced Technologies and Materials

3. Faculty of Science

4. Palacký University

5. CZ-771 46 Olomouc

Abstract

The tetranuclear NiIIcomplexes with the Ni4O4cubane-like core (1) and the Ni4O6defective dicubane core (2) were studied, and the latter identified as a first single-molecule magnet with such topology.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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