Homoleptic trimethylsilylchalcogenolato zincates [Zn(ESiMe3)3]− and stannanides [Sn(ESiMe3)3]− (E = S, Se): precursors in solution-based low-temperature binary metal chalcogenide and Cu2ZnSnS4 (CZTS) synthesis
Author:
Affiliation:
1. Fachbereich Chemie and Materials Science Center
2. Philipps-Universität
3. 35032 Marburg
4. Germany
Abstract
Organic cation salts with homoleptic zincate and stannanide anions, Ph4P [Zn(ESiMe3)3] (E = S (1a), Se (1b)) and Cat [Sn(ESiMe3)3] (Cat = Ph4P+ (E = S (2a-Ph4P); Cat = PPN+ (E = S 2a-Ph4P, Se (2a)) are presented and structurally characterized.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04144C
Reference42 articles.
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3. Zinc Chalcogenolate Complexes as Capping Agents in the Synthesis of Ternary II−II‘−VI Nanoclusters: Structure and Photophysical Properties of [(N,N‘-tmeda)5Zn5Cd11Se13(SePh)6(thf)2]
4. Zinc Chalcogenolate Complexes as Precursors to ZnE and Mn/ZnE (E = S, Se) Clusters
5. ZnS and ZnSe Nanoparticles via Solid-State and Solution Thermolysis of Zinc Silylchalcogenolate Complexes
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