Dual reactivity of B(C6F5)3 enables the silylative cascade conversion of N-aryl piperidines to sila-N-heterocycles: DFT calculations-Reference-Cited by-同舟云学术

Dual reactivity of B(C6F5)3 enables the silylative cascade conversion of N-aryl piperidines to sila-N-heterocycles: DFT calculations

Published:2020 Issue:7 Volume:7 Page:944-952
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhou Miaomiao¹²³⁴,Park Sehoon⁵⁶⁷⁸⁹^ORCID,Dang Li¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province

2. Shantou University

3. Guangdong 515063

4. P. R. China

5. Department of Chemistry

6. Guangdong Technion Israel Institute of Technology

7. Shantou 515063

8. China

9. Technion-Israel Institute of Technology

Abstract

A theoretical study reveals that the dual reactivity of B(C₆F₅)₃ enables the unique silylative cascade conversion of N-aryl piperidines to bridged sila-N-heterocycles.

Funder

National Natural Science Foundation of China

Department of Education of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/C9QO01437C

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