Cyclometallated platinum(ii) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies-Reference-Cited by-同舟云学术

Cyclometallated platinum(ii) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies

Published:2015 Issue:4 Volume:44 Page:1969-1981
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zheng Feng¹²³⁴⁵,Hutton Alan T.¹²³⁴,van Sittert Cornelia G. C. E.⁶⁷⁸⁹⁴,Gerber Wilhelmus J.⁵¹⁰¹¹⁴,Mapolie Selwyn F.⁵¹⁰¹¹⁴

Affiliation:

1. Department of Chemistry

2. University of Cape Town

3. Rondebosch

4. South Africa

5. Department of Chemistry and Polymer Science

6. Catalysis and Synthesis Research Group

7. Chemical Resource Beneficiation Focus Area

8. North-West University

9. Potchefstroom

10. Stellenbosch University

11. Stellenbosch

Abstract

Cyclometallated platinum(ii) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines were synthesised, structurally characterized and their reactivity studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02375G

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1. One-Pot and Step-by-Step N-Assisted CPh−H Activation in 2-(4-Bromophenyl)imidazol[1,2-a]pyridine: Synthesis of a New C,N-Cyclometalated Compound [{Pt(C∧N)(μ-Cl)}2] as Precursor of Luminescent Platinum(II) Compounds

2. A comparative study of the structures and reactivity of cyclometallated platinum compounds of N-benzylidenebenzylamines and cycloplatination of a primary amine

3. Unprecedented intermolecular C–H bond activation of a solvent toluene molecule leading to a seven-membered platinacycle

4. General formation of trigonal-prismatic [Ag6X5(dppf)3]+ (X = Cl, Br, I) through an unusual ligand migration from NiX2(dppf) to AgOTf

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