Copper-catalyzed retro-aldol reaction of β-hydroxy ketones or nitriles with aldehydes: chemo- and stereoselective access to (E)-enones and (E)-acrylonitriles
Author:
Affiliation:
1. The Key Laboratory of Food Colloids and Biotechnology
2. Ministry of Education
3. School of Chemical and Material Engineering
4. Jiangnan University
5. Wuxi 214122
Abstract
A mild and efficient copper-catalyzed retro-aldol reaction of β-hydroxy ketones or nitriles with benzaldehydes produces chemo-, regio- and stereoselectively (E)-enones and (E)-acrylonitriles.
Funder
National Natural Science Foundation of Jiangsu Province
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB01198E
Reference64 articles.
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2. Asymmetric Catalysis of Aldol Reactions with Chiral Lewis Bases
3. Modern Aldol Reactions, ed. R. Mahrwald, Wiley-VCH, Weinheim, Germany, 2004
4. Current progress in the asymmetric aldol addition reaction
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