Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions-Reference-Cited by-同舟云学术

Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions

Published:2018 Issue:12 Volume:42 Page:9645-9650
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sánchez Bruno¹²³⁴⁵^ORCID,Calderón Cristian⁶⁷⁸⁹⁵^ORCID,Garrido Constanza¹²³⁴⁵,Contreras Renato¹²³⁴⁵^ORCID,Campodónico Paola R.⁶⁷⁸⁹⁵^ORCID

Affiliation:

1. Departamento de Química

2. Facultad de Ciencias

3. Universidad de Chile

4. Santiago

5. Chile

6. Centro de Química Médica

7. Facultad de Medicina

8. Clínica Alemana Universidad del Desarrollo

9. Santiago 7710162

Abstract

A biphasic behavior observed on the reaction rate of a model S_NAr reaction in ionic liquid/water mixtures was explained by preferential solvation effects in water rich mixtures, and an anion effect in mixtures with high ionic liquid content.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Ministerio de Economía, Fomento y Turismo

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04820C

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4. Influence of the o-nitro group on base catalysis in nucleophilic aromatic substitution. Reactions in Benzene Solution.

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