A strained intramolecular P/Al-FLP and its reactivity toward allene

Author:

Federmann Patrick1,Bosse Tamino1,Wolff Siad1ORCID,Cula Beatrice1ORCID,Herwig Christian1,Limberg Christian1ORCID

Affiliation:

1. Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany

Abstract

An intramolecular P/Al-based FLP with a biphenylene scaffold is synthesized by a convenient Al-Sn exchange. Despite the spacer the FLP functions interact leading to a strained compound, capable of CO2 binding and unprecedented allene activation.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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