Frustration between two- and three-dimensional smectic ordering leads to a biaxial nematic phase

Author:

Chen Dong12345,Coleman David A.6789,Zhu Chenhui6789,Chattham Nattaporn678910,Jenz Frank678911,Cheng Xiaohong1213141516ORCID,Tschierske Carsten12131415ORCID,Glaser Matthew A.6789,Maclennan Joseph E.6789ORCID,Clark Noel A.6789

Affiliation:

1. Institute of Process Equipment

2. College of Energy Engineering

3. Zhejiang University

4. Hangzhou

5. China

6. Department of Physics and Soft Materials Research Center

7. University of Colorado

8. Boulder

9. USA

10. Department of Physics

11. Institute of Physical Chemistry

12. Institute of Organic Chemistry

13. Martin-Luther-University

14. Halle

15. Germany

16. Department of Chemistry

Abstract

T-shaped bolaamphiphiles develop 2D smectic ordering which is incompatible with the initial lamellar structure, with both structures becoming short-ranged and resulting in a 3D biaxial nematic phase with macroscopic orthorhombic symmetry.

Funder

Division of Materials Research

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference24 articles.

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1. Researches and applications of cholesteric liquid crystal droplets;Chinese Journal of Liquid Crystals and Displays;2022

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