Supramolecular assembly and structural transformation of d10-metal complexes containing (aza-15-crown-5)dithiocarbamate

Author:

Tzeng Biing-Chiau1ORCID,Wu Chung-Lun1,Hung Jun-Wei1,Chien Su-Ying2,Lee Gene-Hsiang2

Affiliation:

1. Department of Chemistry and Biochemistry, National Chung Cheng University, 168 University Road, Min-Hsiung, Chiayi 62102, Taiwan

2. Department of Chemistry, National Taiwan University, 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan

Abstract

[Au(O4NCS2)]2 underwent structural transformation by heating to give [Au(O4NCS2)]6. Moreover, [Ag(O4NCS2)]n and [Cu(O4NCS2)]4 can be isolated, and notably [Cu(O4NCS2)]4 structurally transformed to [Cu(O4NCS2)]8 by heating can be also observed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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