Access to chiral tetrahydrofluorenes through a palladium-catalyzed enantioselective tandem intramolecular Heck/Tsuji

Access to chiral tetrahydrofluorenes through a palladium-catalyzed enantioselective tandem intramolecular Heck/Tsuji–Trost reaction

Published:2019 Issue:26 Volume:55 Page:3769-3772
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Ying¹²³⁴,Shen Hong-Cheng¹²³⁴,Li Yang-Yang¹²³⁴,Huang Yong-Shuang⁵⁶⁷⁸⁴,Han Zhi-Yong¹²³⁴^ORCID,Wu Xiang⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Science and Technology of China

3. Hefei

4. China

5. Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering

6. School of Chemistry and Chemical Engineering

7. Hefei University of Technology

8. Hefei 230009

Abstract

A palladium-catalyzed enantioselective tandem reaction of 2,5-cyclohexadienyl-substituted aryl iodides and carbon or heteroatom nucleophiles has been successfully established by using a chiral H₈-BINOL-based phosphoramidite ligand.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01379B

Reference43 articles.

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